Exploiting the Cheerios effect to study heterogeneous matter
Cheerios floating in a bowl of milk are usually seen to aggregate due to
surface tension. We exploit this effect to study the structure of
heterogeneous agglomerates formed by floating spheres by changing the
level of the liquid in a conical container and thus uniformly
compressing the system. Using this trick we can study aggregates formed
over a wide range of density. We find that the structures are not random
as one may expect for objects brought together randomly, but rather have
local hexagonal structure at short scale and pockets of empty space or
voids. We show with statistical measures that this anomalous behavior is
particularly dramatic at low densities and the system becomes
increasingly homogeneous as the density is increased because of
crowding. Agglomeration due to cohesive interactions occurs broadly in
nature including in dust and soot due to electrostatic interactions,
inter‑galactic dust under gravitation, and in powders due to humidity.
***
LP12468
Materials yield to creep stresses... but not uniformlyIf a bridge or a piece of paper is stressed, it will start slowly to yield, or
creep, by accumulating irreversible deformation. A simple experiment done with
ubiquitous copy paper demonstrates that a sample does not creep uniformly. As
time goes on, the yielding slows down, but fluctuations ‑ differences between
local creep rates and the total one of the sample ‑ become meanwhile larger
and larger relative to the average yield rate. The experiment and simulations
of simple metal plasticity tell us that all this is a result of hidden
complexity inside the material, and related here to a phase transition: if an
object is loaded enough, it will creep until brought to failure, whereas
stresses smaller than a critical value will bring the deformation eventually
to a stop. The results will have an impact on our understanding of the most
important properties of materials, as such variations in creep have a novel
interpretation via a phase transition. They also show how simple, almost toy
experiments, such as pulling a piece of paper, may contain complex, yet
beautiful physics.
Image caption: A copy paper sample under creep due to a constant stress applied
in the vertical direction. The color code shows how the sample deformed over
100 second period of time: from small creep deformation (blue) over to large
deformation (red). In the background one may discern the fibrous,
heterogeneous structure of paper. The non‑uniform deformation shows a signature
of a phase transition, in the collective dynamics of the material.
***
LT12557
Molecules whittled out by x‑rays
The LCLS x‑ray laser at the SLAC National Accelerator Laboratory
is proving its mettle as a machine for discovery in strong field
molecular physics. The first observations of double core
vacancies (DCH) ‑‑ so‑called “hollow atoms,” which have lost
their core electrons ‑‑ were reported in early July in both
Physical Review Letters [Hoener et al.] and in Nature [Young et
al.]. These exotic states should be particularly sensitive
indicators of the chemical environment inside a molecule.
Now barely a month after these first LCLS results, two new
Physical Review Letters are showing the first detailed pictures of
electrons in hollowed out molecules. The Auger electrons, which
boil away from a core‑excited atom with much of the energy
deposited by the x‑rays, are more energetic when there is a
double vacancy. They also retain information about the shape of
the molecule and the distribution of electrons that form the
chemical bonds.
***
LS11930
How to mix immiscible materials down to the atomic scale
The presence and the conditions for the formation of surface alloys on bulk materials or thin films is of utmost scientific and technological importance in various fields of science, such as metallurgy, catalysis or magnetism. Of particular significance is the formation and the understanding of new type of surface alloys from components that are immiscible in the bulk, because new materials with potential for applications may be found.
On a surface, foreign atoms are often stressed due to the atomic size differences with substrate atoms. They can be too much or not enough packed (like apples and cherries in an egg carton). But if we mix big AND small atoms together, we can obtain a good packing if they are correctly ordered. If we make the good choice of constituents and composition of the alloy, we may force two immiscible metals in the bulk to make an ordered surface alloy.
In a recent experiment reported in Physical Review letters (July 2010), two immiscible metal, iron and gold, have been evaporated on a ruthenium surface (which mimics the egg carton) and by choosing a precise ratio of 1/3 a long range ordered bidimensional alloy, has been created and observed with scanning tunneling microscopy and electron diffraction. It was generally accepted that such mixing might be favored because of the strain imposed by the corrugation of the substrate.
This work goes one step further, since the authors have performed state-of-the-art spin-polarized ab initio density functional theory calculations for their system for various atomic configurations and compositions. These calculations show that the driving force for the stability of the ordered alloy is the development of the high Fe atomic moment, i.e. magnetism, while stress relief plays no major role, which is a significant discovery.
These results open up new directions in surface alloying and magnetism, and may lead to the development of technologically relevant alloys for magnetic storage and catalysis.
***
LP12487BR
Probing energy levels of massless electrons at the surface
We present the first observation of magnetic‑field‑quantized energy
levels of a highly unusual electronic state that is formed at the
surface of a newly discovered kind of insulator. Like conventional
insulators, these new insulators are electronically inert in the bulk;
however, so‑called topological insulators can support electrical
conduction ‑ but only at the surface. This surface state is predicted
theoretically to have a number of unusual properties, a striking one of
which is that, just like photons, the mobile electrons at the surface do
not have a mass. Quantum‑mechanical properties of massless electrons are
distinct from those of conventional electrons and this should be
manifest in their quantized energy levels in a magnetic field. Although
it was experimentally verified that the surface electrons are indeed
massless, there has been a lack of studies exploring their quantum
properties due to the inevitable contribution from the bulk electrons in
a real material. Using the surface‑sensitive scanning tunneling
spectroscopy technique in a magnetic field, we selectively probed the
surface massless electrons and successfully detected the quantized
energy levels, with exactly the indexing and field dependence expected
for topological insulators. Present results may provide basis for
understanding topological insulators as well as open several new avenues
for technological exploitation.
***
LQ12706
Attosecond electron interferometry
Ultrafast motion can be captured using ultrashort pulses, which, when it comes to electrons, means that attosecond pulses (1 as = 10-18 s) are necessary. These extremely short pulses have intrinsically very broad bandwidths, which leads to a fundamental problem: they cannot be used directly to resolve the spectral content of an electron wave packet. In this letter we present experimentally a novel technique to overcome this obstacle by utilizing a basic principle of quantum mechanics that continues to fascinate us all: the fact that a coherent addition of different possible electron paths results in high contrast interference fringes. In our experiment these fringes contain state specific amplitude and phase information. We obtain this interference structure by coherently launching a reference wave packet simultaneously with the excitation of the electron wave packet that we want to study. At a later time we recombine the wave packets using a few cycle infrared probe pulse and the interference fringes are recorded as a function of the delay between the two pulses. The presented technique combines high spectral and temporal resolution simultaneously, thus providing an increased precision when doing attosecond experiments.
Please note that in a theoretical work (LR11894) that will be published back to back with our letter the technique has been used to study wave packets created from doubly excited autoionizing states.
***
BRR1130BR
Modeling an unconventional oscillator
In free space, an electron subjected to a static electric field becomes
uniformly accelerated. In a crystalline solid instead, as predicted by
Bloch in 1928, it performs oscillations with a time frequency
proportional to the electric field strength. This spectacular but very
counterintuitive behavior remained a tantalizing concept till Esaki and
Tsu pointed out that a periodic stacking of semiconductor layers of
nanometric dimension (a superlattice) would allow realizing it in
solids. Its implementation has since then been achieved in various
experiments, which unambiguously demonstrate that a Bloch oscillator
excited in a biased superlattice emits light in the THz range, a
frequency domain where reliable and tunable sources are badly lacking.
In our paper we present a modeling of superlattice’s Bloch oscillations
that combines accuracy and flexibility. It is based on a comprehensive
quantum‑optical like description of the superlattice response to a fast
optical pulse and results in the finding of the stronger THz emission.
Such a theoretical strategy fully responds to the present demand of a
dedicated analysis tool. It paves the way to optimizing the emission
characteristics of such fascinating solid‑state oscillators.















